One-step synthesis and structure of an oligo(spiro-orthocarbonate) |
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| Authors: | Vodak David T Braun Matthew Iordanidis Lykourgos Plévert Jacques Stevens Michael Beck Larry Spence John C H O'Keeffe Michael Yaghi Omar M |
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| Institution: | Materials Design and Discovery Group, Deparment of Chemistry, University of Michigan, 930 North University Avenue, Ann Arbor, Michigan 48109, USA. |
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| Abstract: | The reaction of pentaerythritol and tetraethylorthocarbonate at 260 degrees C for 12 h yields a white crystalline material that was characterized by 13C CPMAS NMR, CHN analysis, FT-IR, electron and X-ray powder diffraction, and Rietveld analysis. The white crystalline material was found to have the formula C6H8O4 and a crystal structure with a monoclinic cell a = 9.167 A, b = 5.681 A, c = 5.880 A, beta = 90.0 degrees , space group I2] of hexagonally arranged spiro-oligomeric chains. |
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