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Mechanical behaviour of a poydimethylsiloxane elastomer after outdoor weathering in two different weathering locations
Authors:Panagiota N Eleni  Magdalini K KrokidaGregory L Polyzois  Constantinos A CharitidisElias P Koumoulos  Vasiliki P TsikourkitoudiIoannis Ziomas
Institution:a School of Chemical Engineering, National Technical University of Athens, Zografou Campus, 15780 Athens, Greece
b Department of Prosthodontics, Division of Removable Prosthodontics, Dental School, University of Athens, 2 Thivon Str Goudi, 115 27 Athens, Greece
Abstract:The degradation of maxillofacial prosthetic elastomers that occur during physical weathering is usually responsible for the replacement of the prosthesis. In this study the mechanical behaviour of a polydimethylsiloxane (PDMS) elastomer was investigated, after 1 year outdoor weathering in two different weathering locations in Greece (Thessaloniki, Athens). The hypothesis investigated was that irradiation time did not affect the measured properties. Specimens (Elastomer 42) were prepared according to manufacturer’s instructions and exposed to solar radiation for 1 year. Compression, tensile and nanoindentation tests were performed before and after the exposure. Compression and tensile data were also subjected to analysis of variance (ANOVA) and Tukey Post hoc tests at a level of α = .05. These properties were selected due to their clinical significance for fabrication and maintenance of a facial prosthesis. According to statistical analysis all the measured properties changed significantly after outdoor weathering. More specifically, most of the properties presented significant changes after six months of weathering. The observed changes also depended on the weathering locations. The hypothesis investigated was rejected. Material A became harder and the observed differences in the mechanical behaviour resulted from photo-degradation and hydrolysis that might occur due to weathering. The study also provides new information about maxillofacial prosthetics serviceability obtained from nanoindentation tests.
Keywords:Compression  Nanoindentation analysis  Natural weathering  Polydimethylsiloxane  Tensile testing
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