Reactions of antioxidants with molecular oxygen. Part II. Isooctyl-3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate in silicone matrix |
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Authors: | R Navarro L Audouin J Verdu |
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Institution: | Arts et Métiers ParisTech, CNRS, PIMM, 151 boulevard de l’Hôpital, 75013 Paris, France |
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Abstract: | The study of oxidation kinetics of isooctyl-3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate (Irganox 1135) stabiliser was carried out using silicone oil as an inert substrate. The stabiliser was exposed at 80-120 °C under 0.02-3.0 MPa oxygen pressure. UV/VIS spectrophotometry, gel permeation chromatography and high pressure liquid chromatography were used to follow the stabiliser consumption, whose kinetic parameters were determined by applying a simple kinetic model. |
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Keywords: | Phenolic antioxidant Thermal oxidation Kinetics UV/VIS GPC HPLC |
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