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Limiting Current of Copper Electrodeposition from a Copper Sulfate Solution under Conditions of Natural Convection: The Space Charge Effect
Authors:Grigin  A. P.  Reznikova  L. A.  Tomashova  N. N.  Davydov  A. D.
Affiliation:(1) Frumkin Institute of Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119071, Russia
Abstract:Copper electrodeposition from a copper sulfate solution under conditions of natural convection is analyzed theoretically and examined experimentally. The space charge, which forms in the near-cathode layer, is shown to affect the limiting current density and to change its concentration dependence.
Keywords:electrodeposition  copper  limiting current  natural convection  space charge  electroconvection
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