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Dependence of Fluorescence Properties of Compounds from Psoralen,Angelicin, and Carbazole Series on the Character of Their Terminal Substituents
Authors:Sibirtsev  V. S.  Tolmachev  A. Yu.  Suslov  V. V.  Garabadzhiu  A. V.  Traven'   V. F.
Affiliation:(1) Mendeleev Central Research Institute of Metrology, St. Petersburg, 198005, Russia;(2) Mendeleev Russian Chemical Technological University, Moscow, Russia;(3) St. Petersburg State Technological Institute, St. Petersburg, Russia
Abstract:Absorption, luminescence excitation and emission spectra of nine compounds from 4,8,4'-trimethylpsoralen, 4,4'-dimethylangelicin, and 1,2,3,4-tetrahydrocarbazole series with various terminal substituents were studied in water and 2-propanol. Proceeding from the data obtained in the present and also some previous studies we have formulated the main rules concerning a general mechanism of changes in the fluorescence characteristics of DNA-specific dyes depending on their chemical structure, substrate properties, and measurement medium.
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