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Diode laser absorption spectrum of cold bands of C2HD at 6500 cm
Authors:JL Hardwick  ZT Martin  V Tyng
Institution:a Department of Chemistry, University of Oregon, Eugene, OR 97403-1253, USA
b Department of Physics, University of Oregon, Eugene, OR 97403-1253, USA
Abstract:The absorption spectrum of acetylene-d has been observed at high resolution between 6470 and 6630 cm−1 using an external cavity diode laser. Three cold bands have been observed: the strong 2ν1 band, the weaker ν1 + ν2 + 2ν5 band, and the (ν1 + ν3 + ν5)1 band, which gains its intensity through Coriolis resonance with 2ν1. Centers of unblended lines are determined with an accuracy of approximately 10 MHz.
Keywords:Acetylene-d1  12C2HD  Coriolis coupling  Diode laser spectroscopy
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