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Fourier transform spectroscopy of NiCl: Identification of the [10.3] Φ7/2 state |
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| Authors: | Krystal D Gibbs Leah C O’Brien James J O’Brien |
| Institution: | a Department of Chemistry and Biochemistry and Center for Molecular Electronics, University of Missouri—St. Louis, St. Louis, MO 63121-4499, USA b Department of Chemistry, Southern Illinois University Edwardsville, Edwardsville, IL 62026-1652, USA |
| Abstract: | This paper reports the observation of the 10.3] 4Φ7/2 electronic state of NiCl. This state is identified for the first time through the analysis of an electronic band near 10168 cm−1, namely the 10.3] 4Φ7/2-A2Δ5/2 transition. Molecular parameters for the newly identified 10.3] 4Φ7/2 state are presented. Excited NiCl molecules were produced in a King furnace using NiCl2 heated to 1600 °C. Emission spectra were recorded using the Fourier transform spectrometer associated with the McMath Pierce Solar Telescope at Kitt Peak. |
| Keywords: | Nickel chloride Diatomics High resolution spectroscopy Fourier transform spectroscopy Quartet Φ |
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