Titanium(IV) terminal hydroxo complexes containing chelating bis(phosphine oxide) ligands |
| |
| Authors: | Xiao-Yi Yi |
| |
| Institution: | Department of Chemistry, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong, People’s Republic of China |
| |
| Abstract: | Treatment of LOEtTi(OTf)3] ( , OTf− = triflate) with S-binapO2 (binap = 2,2′-bis(diphenylphosphinoyl)-1,1′-binaphthyl) afforded the terminal hydroxo complex LOEtTi(S-binapO2)(OH)]OTf]2 (1). Treatment of LOEtTi(OTf)3] with K(tpip) (tpip− = N(Ph2PO)2]−) afforded LOEtTi(tpip)(OTf)]OTf] (2) that reacted with CsOH to give LOEtTi(tpip)(OH)]OTf] (3). The structures of 1 and 2 have been determined. |
| |
| Keywords: | Titanium Hydroxo Phosphine oxide Crystal structure |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
