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Synthesis, spectroscopic studies and crystal structure of a polyoxoanion cluster incorporating para-bromophenylimido ligand, (Bu4N)2[Mo6O18(NC6H4Br-p)] |
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| Authors: | Qiang Li Pingfan Wu Yongge Wei Hongyou Guo |
| Affiliation: | a Department of Chemistry, Beijing University of Chemical Technology, Beijing 100029, China b Department of Chemistry, Tsinghua University, Beijing 100084, China c Department of Chemical Engineering, Chengde Petroleum College, Hebei 067000, China d Department of Food Sciences, College of Bioengineering, Hubei University of Technology, Wuhan 430068, China |
| Abstract: | An organic-inorganic hybrid compound, (Bu4N)2[Mo6O18(NAr)] (Ar = p-BrC6H4) has been synthesized via the DCC dehydrating protocol of the reaction of [α-Mo8O26]4− with 4-bromoaniline hydrochloride in anhydrous acetonitrile, which has been characterized by UV-Vis spectra, 1H NMR and single crystal X-ray diffraction study. By comparing the UV-Vis spectra, which were used to monitor the reaction, the optimum preparative condition for this compound was also determined. This compound crystallizes in the monoclinic space group P21/n, which is featured in a terminal para-bromophenylimido group linked to an Mo atom of a hexamolybdate cluster by a Mo-N triply bond. In addition, there are π-π dimerization of the neighboring cluster anions though the parallel aromatic rings in their crystals. |
| Keywords: | Organoimido derivatives Polyoxometalates DCC Aromatic amine halides Organic/inorganic hybrids Crystal structure |
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