Tailoring “non conventional” ionic metallomesogens around an ortho-palladated fragment |
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Authors: | Daniela Pucci Giovanna Barberio Anna Bellusci Alessandra Crispini Mauro Ghedini |
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Institution: | Centro di Eccellenza CEMIF.CAL-LASCAMM, Unità INSTM della Calabria, Dipartimento di Chimica, Università della Calabria, Via P. Bucci Cubo 14/C, I-87030 Arcavacata (CS), Italy |
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Abstract: | A series of new ionic ortho-palladated mesogenic complexes Pd(L)(4,4′-Rn-bpy)]X] of unusual molecular shape have been prepared and characterised. The effect of slight structural changes on the molecular organization in the liquid crystalline phase is discussed in relation with their potential application as molecular materials. |
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Keywords: | Ortho-palladation Bipyridines Phenylpyrimidines Metallomesogens |
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