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Synthesis and applications of optically active metallacycles derived from primary amines
Authors:Joan Albert  Guillermo Muller
Affiliation:Departament de Química Inorgànica, Universitat de Barcelona, Diagonal 647, 08028 Barcelona, Spain
Abstract:The synthesis of optically active cyclopalladated derivatives containing primary amines and their application as resolving agents of Lewis bases is reviewed. Some other applications such as the determination of the absolute configuration of coordinated chiral phosphines and the synthesis of chiral liquid crystals are also presented.
Keywords:Chiral   Primary amine   Palladacycles   Phosphine   Resolution
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