| Lanthanide Complexes with Acetylacetone and 5-(4-Nitrophenyl)-10,15,20-Triphcnylporphyrin Ligands |
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| 作者姓名： | Dong Mei LI Guo Fa LIU Tong Shun SHI Xiao Xun LIU Ji Qing XU |
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| 作者单位： | Department of Chemistry，Jilin University，Changchun，130023 |
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| 摘 要： | Sincethefirstlanthanideporphyrinwassynthesizedin1974',anumberofthisclassofporphyrinshavebeensynthesized'.Becauselanthanideionhasspecialelectronstructure,peopleareinterestedinpropertiesoflanthanideporphyrincomplexessuchascatalyticfunction,opticalstorage,etc3.Ingeneral,moresymmetricallyfunctionallanthanideporphyrinshavebeenstudied,butfewerunsymmetricallanthanideporphyrinsarereported.Nowlanthanidecomplexesofunsymmetricallymeso-substitutedphenylporphyrinacetylacetonate5-(4-nitrophenyl)-10,15,20-tr…
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Lanthanide Complexes with Acetylacetone and 5-(4-Nitrophenyl)-10,15, 20-Triphcnylporphyrin Ligands |
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| Dong Mei LI, Guo Fa LIU, Tong Shun SHI, Xiao Xun LIU, Ji Qing XU.Lanthanide Complexes with Acetylacetone and 5-(4-Nitrophenyl)-10,15,20-Triphcnylporphyrin Ligands[J].Chinese Chemical Letters,1999(2). |
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| Authors: | Dong Mei LI Guo Fa LIU Tong Shun SHI Xiao Xun LIU Ji Qing XU |
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| Abstract: | Five lanthanide porphyrin complexes with 5- (4-nitrophenyl) -10, 15, 20-triphenylporphyrin and acetylacetonate ligands were synthesized and characterized by elemental analysis, IRspectra, Uv-visible spectra, IH NMR. The structures of the complexes were proposed. |
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| Keywords: | lanthanide ion porphyrin complexes |
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