Heterogeneous reactions of solid nickel(II) complexes,III |
| |
Authors: | E Jóna T Šramko J Gažo |
| |
Institution: | 1. Department of Inorganic Chemistry, Slovak Technical University, Bratislava, Czechoslovakia
|
| |
Abstract: | The thermal decompositions of solid complexes of the type Ni(NCS)2L2 (L = pyridine,α-picoline,β-picoline, 2,6-lutidine, and quinoline) were studied by means of the derivatograph. It was found that the decompositions of complexes with pyridine,α-picoline, 2,6-lutidine, and quinoline (the pseudo-octahedral complex) are onestep processes, and those of complexes withβ-picoline and quinoline (the squareplanar complex) consist of two steps. Diffuse reflectance spectra were recorded to elucidate the structures of the decomposition intermediates. The reasons for the different stoichiometries of decomposition for complexes of the same type are discussed. |
| |
Keywords: | |
本文献已被 SpringerLink 等数据库收录! |
|