General approach for the synthesis of polyquinanes |
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| Authors: | M Venkatachalam G Kubiak JM Cook U Weiss |
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| Institution: | Department of Chemistry University of Wisconsin-Milwaukee Milwaukee, Wisconsin 53201 U.S.A.;Laboratory of Chemical Physics National Institute of Arthritis, Diabetes, Digestive and Kidney Diseases Bethesda, Maryland 20205 U.S.A. |
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| Abstract: | The diborane-mediated reduction of labile β-diketones 4, 5 and 6 has been employed as the key step in the synthesis of the three polyquinanes, all--tetracyclo-6.6.0.01,5.08,12]tetradecane 1, all--tricyclo6.3.0.01,5]undecane 2 and all--tetracyclo-5.5.1.04,13.O10,13]tridecane, staurane 3, respectively. |
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