|
|||||
|
|
Chiral propionate enolate equivalent for stereoselective additions to symmetrical ketones |
|
| Authors: | Philip W Ambler Stephen G Davies |
| Institution: | The Dyson Perrins Laboratory, South Parks Road. Oxford. OX1 3QY. U.K. |
| Abstract: | The copper enolate derived from (η5-C5H5)Fe(CO)(PPh3)COCH2CH3 reacts stereoselectively with symmetrical ketones to generate RR,SS-α-methyl-β-hydroxy acyl complexes which on decomplexation liberate the corresponding β-hydroxy acids. |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ | |