Chemical conversion of humulene to dactylol. Biomimetic,apparent 1,2-shift of a methyl group |
| |
| Authors: | Kazuhiro Hayasaka Toshikazu Ohtsuka Haruhisa Shirahama Takeshi Matsumoto |
| |
| Institution: | Department of Chemistry, Faculty of Science, Hokkaido University, Sapporo, 060, Japan |
| |
| Abstract: | Africanol, which had been previously derived from humulene, was converted to dactylol through a formal 1,2-shift of a methyl group, which involved a cyclopropane sliding reaction and subsequent cyclopropane ring opening. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
