The face selectivity directed by an allylic group of a diene in the diels-alder reaction is reversed from that of a dienophile |
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Authors: | Richard W. Franck S. Argade C.S. Subramaniam Denise M. Frechet |
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Affiliation: | Department of Chemistry, Hunter College/CUNY, 695 Park Ave., New York, NY 10021 U.S.A. |
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Abstract: | The Diels-Alder reaction of 2-alkoxy hepta-3,5-dienes with N-phenyl-maleimide gives good diastereofacelectivity; and a face selectivity rule is formulated. |
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