Preparation of the cde-ring system of pleurotin and geogenine via a stereoselective free radical cyclization |
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| Authors: | David J Hart Horng-Chih Huang |
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| Institution: | Department of Chemistry, The Ohio State University, Columbus, Ohio 43210 USA |
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| Abstract: | A synthesis of lactone 3, a projected intermediate in an approach to pleurotin (1) and geogenine (2), is described. The trans-perhydroindan nucleus is constructed using a stereoselective free radical cyclization (5 → 9). |
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