Photochemistry of bis(2-methyl-1-propenyl)ether and 2,2,4,4-tetramethyl-6-oxabicyclo [3.1.0] hexan-3-one: on the search for the oxydi-π-methane rearrangement |
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| Authors: | Waldemar Adam Albrecht Berkessel Stefan Krimm |
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| Institution: | Institut für Organische Chemie, Universität Würzburg, Am Hubland, D-8700 Würzburg, West Germany |
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| Abstract: | π,π-Excitation of bis(2-methyl-1-propenyl)ether leads to products derived from a vinyl-vinyloxy radical pair; photochemical decarbonylation (n,π) of the title ketone provides an entry into the diradical manifold of the oxydi-π-methane rearrangement. |
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