Baker's yeast mediated preparation of carbohydrate-like chiral synthons |
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| Authors: | Giovanni Fronza Claudio Fuganti Piero Grasselli Stefano Servi |
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| Affiliation: | Dipartimento di Chimica del Politecnico, Centro del CNR per la Chimica delle Sostanze Organiche Naturali, 20133 Milano, Italy |
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| Abstract: | Baker's yeast mediated reduction of the α-acetoxy ketones (1)–(3) proceeds with high enantio- and stereoselectivity to give the carbinols (4)–(6), easily converted into the masked chiral deoxy sugars (12)–(14), from which {=D}- and {=L}-deoxysugars have been obtained. |
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