Synthèse rapide et stéréospécifique du (±) α-vétispirène |
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| Authors: | Geneviève Balme |
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| Affiliation: | Laboratoire de Chimie Organique 1, UA. 0467 du CNRS, Université Claude Bernard , 43 Bd du 11 Novembre 1918, 69622 Villeurbanne Cédex, France |
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| Abstract: | A short synthesis of the title compound is described. The key-step involves the treatment of the readily available vinyl-ester by lithium metal in liquid ammonia/THF, then by 5-bromo pent-1-ene so as to effect comcomitant reduction, deoxygenation and stereospecific alkylation in a “one pot process”. |
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