Carbopalladation of β-allenylmalonates : a way to cyclopentenyl or vinylcyclopropyl derivatives. |
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Authors: | Mohammed Ahmar Bernard Cazes Jacques Gore |
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Affiliation: | Laboratoire de Chimie Organique 1, UA 0467 du CNRS, Université Claude Bernard, ESCIL, 43 Bd du 11 Novembre 1918, 69622 Villeurbanne Cedex, France |
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Abstract: | The palladium-catalyzed addition of a vinyl or aryl halide to the enolate of β-allenyl malonate leads to the formation of either of the two cyclized products and depending mainly on the bulk of the starting unsaturated halide. |
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