Reaction of 1-phenyldiazoethane with tetrachloro-p- and o-benzoquinones |
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| Authors: | Takumi Oshima Toshikazu Nagai |
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| Institution: | Institute of Chemistry, College of General Education, Osaka University, Toyonaka, Osaka 560, Japan |
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| Abstract: | Reaction of 1-phenyldiazoethane(1) with tetrachloro-p-benzoquinone(2) gave 1-alkoxy-4-ethenyloxy-tetrachlorobenzene(4). With tetrachloro-o-benzoquinone(5), 1 provided 1-alkoxy-2-ethenyloxy-tetrachlorobenzene(7) and tetrachlorobenzo-1,3-dioxolane(8). The mechanism and the effect of added methanol were discussed. |
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