A stereoselective total synthesis of (±)-oxylubimin |
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Authors: | Chuzo Iwata Yoshiji Takemoto Hitoshi Kubota Takeshi Kuroda Takeshi Imanishi |
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Institution: | Faculty of Pharmaceutical Sciences, Osaka University Yamada-oka, Suita, Osaka 565, Japan |
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Abstract: | (±)-Oxylubimin (1), the highest oxidized spirovetivane-type phytoalexin, was totally synthesized with high stereoselectivity using a novel method for α′-hydroxylation of α,β-unsaturated ketones. |
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