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A stereoselective total synthesis of (±)-oxylubimin
Authors:Chuzo Iwata  Yoshiji Takemoto  Hitoshi Kubota  Takeshi Kuroda  Takeshi Imanishi
Institution:Faculty of Pharmaceutical Sciences, Osaka University Yamada-oka, Suita, Osaka 565, Japan
Abstract:(±)-Oxylubimin (1), the highest oxidized spirovetivane-type phytoalexin, was totally synthesized with high stereoselectivity using a novel method for α′-hydroxylation of α,β-unsaturated ketones.
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