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Diethyl-2,2′-bipyridyl-palladium(II), a case for the study of combination vs. disproportionation products.
Authors:Jürgen Lau  Reiner Sustmann
Institution:Contribution from the Institute for Organic Chemistry, Universität Essen, D-4300 Essen, West Germany
Abstract:Diethyl-2,2′-bipyridyl-palladium(II) is synthesized and its decomposition reactions in absence and presence of methyl acrylate are compared with those of the corresponding nickel and platinum complexes. Depending on the reaction conditions either CC-coupling or disproportionation can be induced.
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