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Dissolving metal reduction with crown ether — reductive decyanation
Authors:Tomihiko Ohsawa  Takao Kobayashi  Yuko Mizuguchi  Takayo Saitoh  Takeshi Oishi
Institution:RIKEN (The Institute of Physical and Chemical Research) Wako, Saitama, 351-01 Japan
Abstract:Toluene radical anion generated from potassium metal/dicyclohexano-18-crown-6/toluene system has been proved to be highly effective for reductive decyanation reaction of primary, secondary and tertiary cyanides.
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