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Novel fluoride transfer in the reaction of tricyclic epoxides with boron trifluoride
Authors:Naotake Takaishi  Hitoshi Takahashi  Yoshiaki Inamoto
Affiliation:Tochigi Research Laboratories, Kao Corporation, 2606 Akabane, Ichikaimachi, Tochigi 321-34, Japan
Abstract:Reaction of the tricyclic epoxides (1a) and (1b) with boron trifluoride etherate leads to fluorohydrins (2a) and (2b) derived in the novel fluoride transfer, whereas (1c) undergoes isomerization to spiro ketone (3).
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