Natural polyene pyrones. Synthesis of the 2,6-dioxabicyclo[3.2.1]octane unit of citreoviridinol |
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Authors: | Martin C. Bowden Gerald Pattenden |
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Affiliation: | Department of Chemistry, The University, Nottingham, NG7 2RD England |
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Abstract: | The 2,6-dioxabicyclo[3.2.1]octane unit, 10, present in citreoviridinol (1) has been produced in a stereoselective manner by treatment of the epoxide (8) derived from citreoviral (6), (7), with -toluenesulphonic acid. |
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