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Natural polyene pyrones. Synthesis of the 2,6-dioxabicyclo[3.2.1]octane unit of citreoviridinol
Authors:Martin C Bowden  Gerald Pattenden
Institution:Department of Chemistry, The University, Nottingham, NG7 2RD England
Abstract:The 2,6-dioxabicyclo3.2.1]octane unit, viz 10, present in citreoviridinol (1) has been produced in a stereoselective manner by treatment of the epoxide (8) derived from citreoviral (6), via (7), with p-toluenesulphonic acid.
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