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Anionic oxycope rearrangements in acetylenic spiro systems |
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| Authors: | V.T. Ravikumar K. Rajagopalan S. Swaminathan |
| Affiliation: | Department of Organic Chemistry, University of Madras Guindy Campus, Madras 600 025, India |
| Abstract: | The anionic oxy-Cope rearrangement of the acetylenic carbinol 3 furnishes the tricyclic diketone 5; substitution at the key position furnishes only the bicyclic 1,3-bridged dione 6. |
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