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18O-tracer study on the rearrangement of carbonyl oxide intermediates to esters |
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| Authors: | Katsuya Ishiguro Kohtaro Tomizawa Yasuhiko Sawaki Hiizu Iwamura |
| Affiliation: | Department of Applied Chemistry, Faculty of Engineering, Nagoya University, Chikusa-ku, Nagoya 464, Japan;Institute for Molecular Science, Myodaiji, Okazaki 444, Japan |
| Abstract: | A tracer study for the rearrangement of carbonyl oxides to esters using doubly-labeled oxygen lead to a conclusion that carbonyl oxides do not isomerize directly to dioxyranes and the rearrangement to esters proceeds via a cyclic tetroxide. |
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