Cleavage of vinyl carbon-silicon bond with tetrabutylammonium fluoride |
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| Authors: | Hiroji Oda Mitsuyoshi Sato Yoshitomi Morizawa Koichiro Oshima Hitosi Nozaki |
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| Institution: | Department of Industrial Chemistry, Faculty of Engineering, Kyoto University, Sakyo-ku, Kyoto 606 Japan |
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| Abstract: | Dimethylphenylsilyl group is removed from a vinyl carbon with tetrabutylammonium fluoride. The presence of phenyl group on silicon atom plays a critical role. The cleavage of allyldimethylsilyl- and alkoxydimethylsilyl groups also proceeds very easily. |
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