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Cleavage of vinyl carbon-silicon bond with tetrabutylammonium fluoride
Authors:Hiroji Oda  Mitsuyoshi Sato  Yoshitomi Morizawa  Koichiro Oshima  Hitosi Nozaki
Institution:Department of Industrial Chemistry, Faculty of Engineering, Kyoto University, Sakyo-ku, Kyoto 606 Japan
Abstract:Dimethylphenylsilyl group is removed from a vinyl carbon with tetrabutylammonium fluoride. The presence of phenyl group on silicon atom plays a critical role. The cleavage of allyldimethylsilyl- and alkoxydimethylsilyl groups also proceeds very easily.
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