Isolation and stereostructures of neocitreoviridinol and epineocitreoviridinol |
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| Authors: | Shigeru Nishiyama Yoshikazu Shizuri Shosuke Yamamura Yukimasa Terada Kazuaki Kawai Hideyuki Furukawa |
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| Institution: | Department of Chemistry, Faculty of Science and Technology, Keio University, Hiyoshi, Yokohama, Japan;Faculty of Pharmacy, Meijo University, Tempaku-ku, Nagoya, Japan |
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| Abstract: | Both neocitreoviridinol and epineocitreoviridinol with a 2,5-dioxabicyclo2.2.1]-heptane ring have been isolated as new metabolises of B., and their stereostructures have also been elucidated on the basis of their spectral data coupled with molecular mechanics calculations. In addition, a promising synthetic intermediate for neocitreoviridinol has been made. |
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