Conformational effects in organoaluminum-promoted pinacol-type rearrangement |
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| Authors: | Keisuke Suzuki Katsuhiko Tomooka Masato Shimazaki Gen-ichi Tsuchihashi |
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| Affiliation: | Department of Chemistry, Faculty of Science and Technology, Keio University, Hiyoshi, Yokohama 223, Japan |
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| Abstract: | Conformational effects on the reaction course were examined in organoaluminum-promoted pinacol-type rearrangement, using stereo-defined unsymmetrical β-mesyloxy alcohols as the probe, where combinational use of DIBAL-Et2AlCl achieved highly selective migration. |
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