Some properties of radical reactions important in synthesis |
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Authors: | Cheves Walling |
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Affiliation: | Department of Chemistry, University of Utah Salt Lake City, UT 84112, U.S.A. |
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Abstract: | Properties of radical chain reactions are reviewed including propagating steps, lifetimes of chains, and choices of initiators. Structure and reactivity relations in chain-propagation steps and their effects on regio- and stereochemistry are discussed. The utility of redox chains involving transition metal ions is considered along with the importance of radical ions as reaction intermediates. |
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