The stereochemistry of the hydroboration rearrangement. |
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| Authors: | Leslie D Field Stephen P Gallagher |
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| Affiliation: | Department of Organic Chemistry, University of Sydney, Sydney 2006, New South Wales, Australia. |
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| Abstract: | Hydroboration of 1,2-dimethylcyclopentene with BH3·THF affords a product in which boron migrates at low temperature into the cyclopentane ring. At higher temperatures subsequent (non-stereospecific) isomerisation occurs via a competing reaction mechanism. |
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