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Action des sulfonyloxaziridines sur une imine. Obtention d'une nitrone par transfert regioselectif de l'oxygene sur l'azote
Authors:Pierre Milliet  Xavier Lusinchi
Affiliation:Institut de Chimie des Substances Naturelles, CNRS, 91190 Gif-sur-Yvette, France
Abstract:A pyrrolinic imine has been found to react concurrently with the nitrogen or the oxygen of a N-sulfonyl oxaziridine leading to a N-sulfonyl diaziridine and a nitrone respectively. By contrast an oxaziridine is obtained with a peracid. A possible relation between the regioselectivity of the oxygen transfer and the nature of the reagent is outlined.
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