Action des sulfonyloxaziridines sur une imine. Obtention d'une nitrone par transfert regioselectif de l'oxygene sur l'azote |
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Authors: | Pierre Milliet Xavier Lusinchi |
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Affiliation: | Institut de Chimie des Substances Naturelles, CNRS, 91190 Gif-sur-Yvette, France |
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Abstract: | A pyrrolinic imine has been found to react concurrently with the nitrogen or the oxygen of a -sulfonyl oxaziridine leading to a N-sulfonyl diaziridine and a nitrone respectively. By contrast an oxaziridine is obtained with a peracid. A possible relation between the regioselectivity of the oxygen transfer and the nature of the reagent is outlined. |
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