Regio- and stereodefined synthesis of trimethylsilyl enol ethers resulted from the isomerization of α-trimethylsilyl ketones |
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| Authors: | Isamu Matsuda Susumu Sato Motoaki Hattori Yusuke Izumi |
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| Institution: | Department of Synthetic Chemistry, Faculty of Engineering, Nagoya University, Chikusa, Nagoya 464, Japan |
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| Abstract: | The isomerization of an α-trimethylsilyl ketone is lead to the corresponding trimethylsilyl enol ether with the enhanced regioselectivity by heating or by the assist of trimethylsilyl trifluoromethanesulfonate. The thermal reaction discloses a new regiodefined (E)-selective route to silyl enol ethers. |
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