A novel stereoselective synthesis of 1,3,5-trienes via so2 extrusion from sulfolenes. |
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| Authors: | R. Bloch C. Benecou E. Guibé-Jampel |
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| Affiliation: | Laboratoire des Carbocycles, UA 478 du CNRS, Université de Paris-Sud, Bâtiment 420 91405 Orsay Cedex, France |
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| Abstract: | (E)-1,3,5-hexatriene as well as (E,E)-1,3,5-undecatriene and (E,Z)-1,3,5-undecatriene, two natural compounds isolated from the essential oils of and , were stereoselectively synthesized from sulfolenes generated by a retro-Diels-Alder reaction. |
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