Chiral propionate enolate equivalents for the stereoselective synthesis of <em>threo</em>- or <em>erytho</em>-α,-methyl-β-hydroxy acids期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

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*Chiral propionate enolate equivalents for the stereoselective synthesis of threo- or erytho-α,-methyl-β-hydroxy acids*

Authors:	Stephen G Davies Isabelle M Dordor-Hedgecock Peter Warner

Institution:	The Dyson Perrins Laboratory, South Parks Road, OXFORD. U.S.A.

Abstract:	The aluminium and copper enolates derived from (η⁵-C₅H₅)Fe(CO)(PPh₃)COCH₂CH₃ are chiral propionate enolate equivalents which on reaction with aldehydes (RCHO, RMe.Et,ⁱPr,^tBu) provide stereoselective syntheses of threo- and erytho-α-methyl-β-hydroxy acids respectively.

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