Mild reaction of pummerer rearrangement products with aromatic compounds in the presence of lewis acids. Application to the preparation of arylmethylene ketones,arylacetoesters, and arylacetonitriles. |
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| Authors: | Ioannis K Stamos |
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| Institution: | The National Hellenic Research Foundation, 48 V. Konstantinou Ave., Athens 11635, Greece. |
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| Abstract: | Pummerer intermediates generated from precursors (3), (4) and (5) reacted mildly with aromatic compounds in the presence of Lewis acids to give the corresponding sulfides which in turn desulfurized to arylmethylene ketones, arylacetoesters, and arylacetonitriles. |
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