,-dienes via acetylene carbocupration: synthesis of navel orangeworm pheromone |
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Authors: | Mark Furber Richard J.K. Taylor S.Cliff Burford |
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Affiliation: | 1. School of Chemical Sciences, University of East Anglia, Norwich, NR4 7TJ U.K.;2. Fisons Pharmaceutical Division, Loughborough LE11 ORH U.K. |
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Abstract: | A range of conjugated ,-dienes have been prepared in a stereo-specific manner acetylene carbocupration: the value of this procedure has been illustrated by an extremely short synthesis of hexadeca-11, 13-dienal a principle component of Navel Orangeworm Pheromone. |
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