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Z,Z-dienes via acetylene carbocupration: synthesis of navel orangeworm pheromone
Authors:Mark Furber  Richard JK Taylor  SCliff Burford
Institution:1. School of Chemical Sciences, University of East Anglia, Norwich, NR4 7TJ U.K.;2. Fisons Pharmaceutical Division, Loughborough LE11 ORH U.K.
Abstract:A range of conjugated Z,Z-dienes have been prepared in a stereo-specific manner via acetylene carbocupration: the value of this procedure has been illustrated by an extremely short synthesis of hexadeca-11Z, 13Z-dienal a principle component of Navel Orangeworm Pheromone.
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