Synthesis of a versatile functionalized tetraquinane. Convenient access to 1,3-bishomopentaprismanedione |
| |
| Authors: | Leo A Paquette Koichi Nakamura John W Fischer |
| |
| Institution: | Evans Chemical Laboratories, The Ohio State University, Columbus, Ohio 43210 USA |
| |
| Abstract: | The tetracyclic diene dione 1 has been synthesized by a short oxidative decarboxylation route starting with the domino Diels-Alder adduct 2. Photocyclization of the bisketal of 1 was used to arrive expediently at 1,3-bishomopentaprismanedione (7). |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
