Synthesis of a versatile functionalized tetraquinane. Convenient access to 1,3-bishomopentaprismanedione |
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Authors: | Leo A Paquette Koichi Nakamura John W Fischer |
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Institution: | Evans Chemical Laboratories, The Ohio State University, Columbus, Ohio 43210 USA |
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Abstract: | The tetracyclic diene dione 1 has been synthesized by a short oxidative decarboxylation route starting with the domino Diels-Alder adduct 2. Photocyclization of the bisketal of 1 was used to arrive expediently at 1,3-bishomopentaprismanedione (7). |
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