A highly efficient synthetic route to ketones through sequential coupling reactions of grignard reagents with -phenyl carbonochloridothioate in the presence of nickel or iron catalysts |
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Authors: | C. Cardellicchio V. Fiandanese G. Marchese L. Ronzini |
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Affiliation: | Centro CNR di Studio sulle Metodologie Innovative di Sintesi Organiche dipartimento di Chimica, Università di Bari, Via Amendola, 173 70126 Bari, Italy |
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Abstract: | The sequential coupling reactions of Grignard reagents with phenyl carbonochloridothioate in the presence of nickel(II) or iron(III) catalysts provides a very mild and straightforward route to symmetrical and unsymmetrical aliphatic and aromatic ketones. |
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