Synthetic studies on arene-olepin cycloadditions-VII:1 a three-step total synthesis of (±)-silphinene |
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| Authors: | Paul A. Wender Robert J. Ternansky |
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| Affiliation: | Department of Chemistry, Stanford University, Stanford, California 94305 USA |
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| Abstract: | A three-step total synthesis of (±)-silphinene () is described which illustrates the high process selectivity attainable with the arene-olefin metaphotocycloaddition and a method for selective transformation of metacycloadducts. |
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