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Cobalt carbonyl catalyzed reaction of tetrahydrofurans with a hydrosilane and carbon monoxide. A new reaction pathway leading to enol silyl ethers.
Authors:Toshiaki Murai  Shinzi Kato  Shinji Murai  Yoshio Hatayama  Noboru Sonoda
Affiliation:Department of Chemistry, Faculty of Engineering, Gifu University, Yanagido, Gifu 501-11, Japan;Department of Applied Chemistry, Faculty of Engineering, Osaka University, Suita, Osaka 565, Japan
Abstract:Cobalt carbonyl catalysed reaction of tetrahydrofurans with HSiEt2Me and CO (1 atm) took a new reaction pathway leading to enol silyl ethers when acetonitrile was employed as the solvent.
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