Eliminative deoxygenation: A facile synthesis of α-cyano and α-carboalkoxy substituted vinyl sulfides |
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Authors: | R.D. Miller R. Hässig |
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Affiliation: | IBM Research Laboratory, San Jose, California 95193 U.S.A. |
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Abstract: | The faciIe eliminative deoxygenation of α-cyano and carboalkoxy sulfoxides by trimethylsilyl triflate under mildly basic conditions results in the formation of α-thiophenyl substituted α,β-unsaturated nitriles and esters in high yields. |
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