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Eliminative deoxygenation: A facile synthesis of α-cyano and α-carboalkoxy substituted vinyl sulfides
Authors:RD Miller  R Hässig
Institution:IBM Research Laboratory, San Jose, California 95193 U.S.A.
Abstract:The faciIe eliminative deoxygenation of α-cyano and carboalkoxy sulfoxides by trimethylsilyl triflate under mildly basic conditions results in the formation of α-thiophenyl substituted α,β-unsaturated nitriles and esters in high yields.
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