ETAAS determination of Cd and Pb in plants |
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Authors: | I Karadjova and M Karadjov |
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Institution: | (1) Faculty of Chemistry, University of Sofia, BG-1126 Sofia, Bulgaria, BG;(2) Geological Institute, Bulgarian Academy of Science, BG-1113 Sofia, Bulgaria, BG |
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Abstract: | Simple and rapid analytical procedures for the ETAAS determination of Cd and Pb in plant (poplar, clover, plantain) leaves
are described. Optimal conditions are presented for the wet digestion of plant matrices with a mixture of nitric acid and
hydrogen peroxide along with optimal temperature programmes for subsequent modifier-free electrothermal determination of Cd
and Pb. Slurry preparation procedures using tetramethylammonium hydroxide or a mixture of 1 mol/L HNO3 + 1.5 mol/L H2O2 are proposed as another approach for rapid and accurate routine analysis of Cd and Pb in plant leaves. It has been found
that single standard addition can be used for quantitative determination in the case of wet digestion ETAAS and standard addition
to each analysed matrix is recommended in the case of slurry ETAAS. For all plant leaves investigated good agreement was achieved
between the concentrations determined by wet digestion ETAAS and slurry ETAAS. The wet digestion method provides relative
standard deviations for Cd ranging from 3% to 17% and for Pb from 2% to 16%. For the slurry method the RSD values are in the
range of 4–31% for Cd and 4–30% for Pb, depending for both cases on the magnitude of the measured concentrations. Validity
and versatility of the methods are verified by the analyses of standard reference materials.
Received: 17 March 1997 / Revised: 2 May 1997 / Accepted: 8 May 1997 |
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